The -matrix permits the calculation of two types of observable
quantities, lifetimes and cross-sections.
Both can be calculated from the transition probability per unit
space-time volume.
If there were no interaction between the particles, the state of the
system would be unchanged, corresponding to a unit
-matrix (absence
of scattering).
It is convenient to separate this unit matrix in all cases, writing
the scattering matrix in the form
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|
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(7.1) |
where is another matrix.
In the second term we have written separately the four-dimensional
Dirac delta-function which comes from the integral
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(7.2) |
The Dirac delta-function expresses the law of conservation of
four-momentum ( and
being the sums of the four-momentum of
all the particles in the final and initial states), the other factors
are included for subsequent convenience.
If one of the colliding particles is sufficiently heavy (and its
state is unaltered by the collision) it acts only as a fixed source of
a constant field in which the other particle is scattered.
Since the energy (though not the momentum) of the system is conserved
in a constant field, in this treatment of the collision process we
can write the -matrix elements in the form
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(7.3) |
The structure of the scattering amplitude is of the form
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(7.4) |
where on the left we have the amplitude of wave functions of final
particles, and on the right those of initial particles; is some
matrix relating the indices of the wave amplitude components of all the
particles.
Consider the transition of a system from an initial state to a
final state
.
The matrix element of
may then be replaced by that of
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(7.5) |
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(7.6) |
In momentum space the matrix elements of the operator are of the
form
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(7.7) |
where and
are the initial and final four-momentum of the
system.
is the transition probability amplitude for a transition taking
place over all space and all time from the infinite past to the infinite
future.
The corresponding transition probabability,
, is not a
meaningful quantity (and not at all a probability), since observations
are carried out over finite times and only the transition probability
per unit time is essentially measureable.
Indeed,
is infinite and simply experesses the fact that,
during an infinite time, a nonzero incident flux of particles will cause
an infinite number of repetitions of the elementary process under
consideration.
Hence the interesting quantity is the transition probability per unit
time, or for convenience in our covariant formalism, the transition
probability per unit space-time volume, .
The latter can be obtained as a limit from finite space-time volume
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(7.8) |
Here,
is
calculated for a finite
space-time volume
.
We remember that the expression for results from an
integration over infinite space-time
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(7.9) |
Therefore
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(7.10) |
When the moduli are squared, the square of the delta
function appears, and is to be interpreted as follows.
If another such integral is calculated with
(since one delta
function is already present), and if the integral is taken over some
large finite volume
and time interval
, the results is
.
The evaluation of involoves the limit
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(7.11) |
We find for the transition probability per unit space-time volume
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(7.12) |
still depends on the details observed in the experiments.
For example, if the polarization of the outgoing electron is not
observed, a summation over the final polarization states must be
carried out.
For the inital states, a suitable average must be found.
Let indicate a generalized summation symbol representing integration
over momenta and summations over spins and polarizations, depending on
the type of process
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(7.13) |
where the bar over indicates the average process.
For the cross-section, we take a incoherent average, in the sense that
we average the cross-section rather than the amplitude.
In our expression it is not necessary to restrict the consideratons to a single initial electron, positron, or photon. Let us then consider one single initial system. The transition probability per unit time into all other possible states will be
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(7.14) |
The most important cases are those where the initial state comprises
only one or two particles: decays and scattering respectively.
We can form simplified expressions for special cases like a two-body
decay or a
process.
We see that
is independent of
.
Its inverse,
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(7.15) |
is called the lifetime of the system.
Consider the case of two systems of particles.
In the centre-of-momentum system,
.
The flux density of particles
is determined by the velocities
.
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(7.16) |
This last expression can be written in such a way that it is valid in any reference system.
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(7.17) |
where
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(7.18) |
On the other hand, in the rest-frame of system 1 (), we obtain
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(7.19) |
and
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(7.20) |
If one of the systems (system 1 say) is a set of photons
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(7.21) |
and
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(7.22) |
If both systems are photons then, in the center-of-momentum system
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(7.23) |
The ratio of the transition probability per unit volume, , and
the flux density in the initial state,
, is called the cross-section
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(7.24) |
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(7.25) |
According to the summation in there exists various partial
cross-sections.
If the momentum vectors of the final state fall within certain
differential range we use the term differential cross-sections.
We will now develop the practical abilities to calculate lowest-order quantum electrodynamical processes (figure 7.1). That is, we will apply the propagator formalism to problems involving electrons, positrons, and photons. As we go, we will derive general rules for the calculation of transistion probabilities and cross sections: the Feynman rules.